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Silicate cements(Sylycyn, Fritex)
For root seals. Requirements to sealing materials for permanent seals · Not to be dissolved in oral liquid · To harden in the presence of moisture · The factor of thermal expansion should be similar to factor of thermal expansion of enamel and dentine · To possess insignificant heat conductivity and minimum water absorption · To be indifferent to tooth tissues, non-toxic · To possess durability similar to durability of enamel of a tooth · To be erased slowly · To be cosmetic, X-ray contrast To possess high adhesion to firm tissues of a tooth. Cements (D. S. Smith, 1995): · Phosphatic – (Zinc-phosphatic, Silico-phosphatic, Silicate) · Phenol- (Zinc-eugenol, Ca (OH) 2 Salycylatic) · Polycarboxylate (Zinc- polycarboxylate, Glass-ionomer) · Acrylic (Polymetacrylic, Dimethylacrilic)
Cements on the basis of phosphates Zinc-phosphatic cements (ZPC, Phosphate-cement, Adhesor) 1. Structure: powder - oxide zinc, 10 % oxide magnesium. 2. Liquid - water solution of phosphoric acid, 2-3 % aluminium, 0-9 % zinc. 3. Advantages: Easy to work, hardens fast, relative durability, good isolating properties, small toxicity. 4. Disadvantages: absence of antibacterial effect, fragility, weak adhesion, solubility in an oral liquid. 5. Use: lining for pulp protection, constant seals in temporary teeth at stage of root resorption, temporary seals. Silico-phosphatic cements ( Sylydont, Infantid, Lumikolor Cement) 1. Structure: powder - 10-20 % oxide zinc, silicate glass (12-25 % fluoride). Liquid - a solution orthophosphoric acid, containing 45 % of water, 2-5 % aluminium and zinc 2. Advantages: durability, partial transparency, anti-carious action. 3. Disadvantages: high acidity of a seal toxic action on a pulp. 4. Use: sealing of cavities of the I-st, II-nd classes. 1. Structure: powder - 29-47% Si02, 15-35% Al203, 0,27-14% CaO, 5-15%. Liquid – solution of the phosphoric acid, containing aluminium, zinc and magnesium phosphate. 2. Advantages: anti-carious action, transparency, durability. 3. Disadvantages: solubility in an oral liquid, low adhesion, toxicity, fragility. 4. Use: sealing of cavities of the III-d, IV-th, V-th classes. Phenol cements This class concerns: · simple combination of zinc and eugenol; · materials on a basis of zinc-eugenol with filler. Zinc-eugenol ( Caryosan, Zinoment) 1. Structure: powder - oxide zinc, liquid - purified eugenol or Carnation oil. 2. Advantages: good hermetic sealing of carious cavities, anti-inflammatory and plastic-stimulating action. 3. Disadvantages: low durability, slows down polymerisation of composit materials. 4. Use: time sealing, linings for pulp protection. Zinc-oxide eugenol cements with filler 1. Structure: powder oxide zinc, 10-40 % rosin or synthetic pitches, catalysts.Liquid - cleared eugenol or Carnation oil (may contain acetic acid, tymol). 2. Advantages: antiseptic action, low heat conductivity. 3. Use: linings for pulp protection, time sealing. Ca(OH)2 Salycylatic – (Calxyd, Dycal, Calcimol - self-cured materials; Lica, Ultra Blend Plus - light cured materials). 1. Advantages: anti-inflammatory and plastic-stimulating action. 2. Disadvantages: high solubility, low durabiliti. 3. Use: linings for pulp protection. Poly-carboxyl cements 1. Structure: oxide zinc powder, 1-5 % oxide magnesium, liquid - 40 % water solution of polyacryle acid or copolymer of acryle acids. 2. Advantages: good adhesion to tooth tissues, hardness, ease to work. 3. Disadvantages: high solubility in an oral liquid, low adhesion. 4. Use: linings for pulp protection, time sealing. Glass-ionomer cements. 1. Structure: powder Si02-Al203-CaF, Al (PO)4 Na3A1F3; Al203/SIO2=1:2,F to 23 %. Liquid - a copolymer polyacryle acid or ordinary water. 2. Advantages: chemical adhesion to dentine and to the majority of stomatological materials, factor of thermal expansion similar to to a factor of enamel and dentine, low solubility after becoming hard, X-ray contrast, biocompatibility with tooth tissues. 3. Disadvantages: fragility, insufficient aesthetics. 4. Use: sealing non-carious impairment of solid tissues of the teeth, sealing of a root's caries, temporary (kept away for 1-2 years) sealing of a permanent teeth, caries treatment with ART techniques, sealing carious cavities of all classes in temporary teeth. Types of glass-ionomer cements: - fixing (Ketac-Cem, Fuji Ortho, Fuji I (GC)); - for restoration; - for linings (Aqua Cent); - for aesthetic restorations (Ketac-Fil, Ketac-Molar, Fuji II, Fuji IX (GC), Ionofil (VOCO)).
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